I tried a lot to enable hotspot through the GUI of Network Manager but it never happened. It created a hotspot but always the created hotspot didn't even appear in my android phone. Sometimes it is a problem in Ubuntu14.04. Same user interface worked for enabling hotspot in 13.10.Here are the steps that will guide you to enable hotspot and connect with other devices.You need to add a repository online, so make sure that you are using internet
tech@jhola:~$ sudo add-apt-repository ppa:nilarimogard/webupd8 Update the whole list of repositories
tech@jhola:~$sudo apt-get update Adding the repository adds ap-hotspot to the list, Now install ap-hotspot
tech@jhola:~$sudo apt-get install ap-hotspot ap-hotspot is now installed. Better open,configure and start the hotspot service
tech@jhola:~$sudo ap-hotspot
tech@jhola:~$sudo ap-hotspot configure
tech@jhola:~$ sudo ap-hotspot start
After HOTSPOT is created
In case you want to see the devices that are connected to your hotspot use this command
tech@jhola:~$ arp -a